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I stumbled on this thread in 2014, long after the original posting, as I was looking for flame resistant sports bras and this thread came up in search.
I have found three options. From least to most expensive, they are:
Here's a link to a study by the Forest Service, "Tests of Undergarments Exposed to Fire."
http://www.fs.fed.us/t-d/pubs/pdfpubs/pdf08512348/pdf08512348dpi72.pdf
the best flame resistant material for clothing such as underwear and bras is the old standard cotton.
anything else would be too flammable to wear in a fire situation or arc flash incident.
while tight woven wool is also good it would be heavy and uncomfortable.
i forgot to add while there are specialty wear out there they are also prohibitively expensive
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